Again: what is 172.1.1.1 - 172.224.224.224 supposed to achieve? That is not how IP addressing works.172.0.0.0-172.255.255.255 or 172.0.0.0/8
As the docs states, 200.1.1.1-200.225.225.225 should work for HOSTS, but maybe not for NETWORKS.You also should kill states after applying deny rules.