Hi! The IPv6 /48 that you have, is it allocated to you with no other facilities, or does it come from your ISP via IPv6 Prefix Delegation?
If you're getting it from the ISP via Prefix Delegation, then you don't need to actually configure DHCPv6 on OPNsense; you set the LAN IPv6 interface to track the PPPoE WAN, and that should automagically work.