This causes an issue with dpinger gateway monitoring, a workaround is to use another target address such as one of the google DNS server addresses, note if you use multwan do not use the same address for both v6 monitors, also if you are using googles DNS for resolution then find some other WAN v6 targets.
EDIT: @andreaslink - can you try disabling Static route filtering on the Firewall->Advanced page, I've seen this fix the issue for some.
I'm slightly puzzled, what could prevent the IPv6 connection here. I'm considering setting up a fresh install as this one is already updated since quite some years now.